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What is true phase equilibrium?

asked Dec 27, 2015 in Process by anashi (710 points)

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answered Dec 27, 2015 by ChemKB (8,210 points)
Equality of fugacity is a neccesary,but not sufficient, condition as it may correspond with a local minimum in the Gibbs free energy of the mixture, whilst a global minimum refers to the true equilibrium.

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